Protactinium Basis-Sets:


Pa_ERD_SMALL_CORE_PP_4F_IN_VALENCE_NO_G_2017

291 9
INPUT
31. 0 1 1 1 1 1
 15.26917367 475.47573283 0
 9.957736990 207.66485962 0
 8.943141260 156.67411988 0
 7.010466620 67.982236850 0
 12.20105601 -57.63059989 0
0 1 5 8.0 1.0
 132.7511064660 0.01535393080080 0.002566011868100
 37.91566125830 -0.1944925632820 -0.00234865201565
 18.95369736660 1.22113546279000 0.052094603756300
 9.130435095820 -2.1716075640100 -0.20611727444600
 5.511675326660 -0.8395336060400 -0.22218157184800
0 1 3 8.0 1.0
 7.875505798030 -0.2571179964810 0.010428352772800
 3.730676999440 0.73350782133900 0.436890250274000
 1.715251199100 0.58354507320500 0.390919940442000
0 1 2 0.0 1.0
 1.421438232030 -0.0925432185809 0.175186984326000
 0.552935396821 1.12815467056000 0.914686850567000
0 1 1 0.0 1.0
 0.212213818995 1.00000000000000 1.000000000000000
0 3 6 10.0 1.0
 22.78579942410 0.01198546907490
 8.854266427700 -0.1114413100610
 3.936019456220 0.30292231194000
 2.250463794050 0.45712115741400
 1.235835442690 0.31840148139600
 0.811034611243 0.03608858956160
0 3 1 0.0 1.0
 0.414217466663 1.00000000000000
0 4 4 2.0 1.0
 54.35404142480 0.00127741955136
 19.99005693100 0.01096922746880
 6.594422584120 -0.0282040090652
 4.755504162320 0.26566278236600
0 4 3 0.0 1.0
 2.246275051280 0.30802528379200
 1.037488617700 0.36135930858700
 0.479582893208 0.27448399902400
0 4 1 0.0 1.0
 0.203495817705 1.00000000000000



Optimized basis set for Pa3+ without g (+ more diffuse exponents optimized on Pa2O3 hexagonal peridodic structure)

used in:
1)  Kh. E. El-Kelany, C. Ravoux, J. K. Desmarais, Y. Pan, J. S. Tse, R. Dovesi, and A. Erba, "Magnetic Ordering and Electronic Properties of Strongly Correlated Ln2O3 Sesquioxides (Ln=La, Ce, Pr, Nd)" in preparation

2) J. K. Desmarais, A. Erba, and R. Dovesi, Theor. Chem. Acc. (2018) "Generalization of the Periodic LCAO Approach in the CRYSTAL Code to g-type Orbitals" submitted


Pa_ERD_SMALL_CORE_PP_4F_IN_VALENCE_2017

291 11
INPUT
31. 0 1 1 1 1 1
 15.26917367 475.47573283 0
 9.957736990 207.66485962 0
 8.943141260 156.67411988 0
 7.010466620 67.982236850 0
 12.20105601 -57.63059989 0
0 1 5 8.0 1.0
 132.7511064660 0.01535393080080 0.002566011868100
 37.91566125830 -0.1944925632820 -0.00234865201565
 18.95369736660 1.22113546279000 0.052094603756300
 9.130435095820 -2.1716075640100 -0.20611727444600
 5.511675326660 -0.8395336060400 -0.22218157184800
0 1 3 8.0 1.0
 7.875505798030 -0.2571179964810 0.010428352772800
 3.730676999440 0.73350782133900 0.436890250274000
 1.715251199100 0.58354507320500 0.390919940442000
0 1 2 0.0 1.0
 1.421438232030 -0.0925432185809 0.175186984326000
 0.552935396821 1.12815467056000 0.914686850567000
0 1 1 0.0 1.0
 0.212213818995 1.00000000000000 1.000000000000000
0 3 6 10.0 1.0
 22.78579942410 0.01198546907490
 8.854266427700 -0.1114413100610
 3.936019456220 0.30292231194000
 2.250463794050 0.45712115741400
 1.235835442690 0.31840148139600
 0.811034611243 0.03608858956160
0 3 1 0.0 1.0
 0.414217466663 1.00000000000000
0 4 4 2.0 1.0
 54.35404142480 0.00127741955136
 19.99005693100 0.01096922746880
 6.594422584120 -0.0282040090652
 4.755504162320 0.26566278236600
0 4 3 0.0 1.0
 2.246275051280 0.30802528379200
 1.037488617700 0.36135930858700
 0.479582893208 0.27448399902400
0 4 1 0.0 1.0
 0.203495817705 1.00000000000000
0 5 1 0.0 1.0
 0.900000000000 1.00000000000000
0 5 1 0.0 1.0
 0.300000000000 1.00000000000000


Optimized basis set for Pa3+ with g (+ more diffuse exponents optimized on Pa2O3 hexagonal peridodic structure)

used in:
1)  Kh. E. El-Kelany, C. Ravoux, J. K. Desmarais, Y. Pan, J. S. Tse, R. Dovesi, and A. Erba, "Magnetic Ordering and Electronic Properties of Strongly Correlated Ln2O3 Sesquioxides (Ln=La, Ce, Pr, Nd)" in preparation

2) J. K. Desmarais, A. Erba, and R. Dovesi, Theor. Chem. Acc. (2018) "Generalization of the Periodic LCAO Approach in the CRYSTAL Code to g-type Orbitals" submitted