Polonium Basis-Sets:


Po_pob_TZVP_rev2

284 12
INPUT
24. 0 2 4 4 4 2
 13.277227 283.244706 0
  8.399518  62.396461 0
 10.665682  71.991716 0
  9.283753 143.971871 0
  6.872749   4.949615 0
  6.326150   9.740499 0
  8.214866  36.378383 0
  8.008696  54.562715 0
  5.055227   9.889499 0
  4.782553  14.693877 0
  5.013270  17.428295 0
  4.984640  23.380353 0
  1.326760   0.163392 0
  1.528758   0.324566 0
  6.771526 -11.563294 0
  6.777925 -14.509788 0
0 0 5 2 1.0
  6744.82117650       0.000076891556
  744.418925320       0.000712848274
  131.040293090       0.002205758396
  19.6620210300      -0.643647137440
  16.6230256090       0.919971505460
0 0 2 2 1.0
  23.0940029650      -0.070404410177
  6.97073983810       0.978865400860
0 0 2 0 1.0
  1.84973776000       0.675853246983
  0.93082999000       0.324146753017
0 0 1 0 1.0
  0.26927938000       1.000000000000
0 2 3 6 1.0
  253.990244970       0.000083876362
  9.87127187480       0.245727104580
  7.44898934960      -0.442977636610
0 2 4 4 1.0
  8.90273954070      -0.137982504450
  5.74146674650       0.263040053260
  1.98963298230       0.662258461610
  0.94703210822       0.395470518920
0 2 1 0 1.0
  0.35554706000       1.000000000000
0 2 1 0 1.0
  0.15021472000       1.000000000000
0 3 6 10 1.0
  67.9430770460       0.000489191253
  14.9142198940       0.010157120776
  7.29739483050      -0.069943263066
  2.68267844000       0.262447306800
  1.43741430090       0.427023614940
  0.73903797417       0.325024354770
0 3 1 0 1.0
  0.66169712000       1.000000000000
0 3 1 0 1.0
  0.34810921000       1.000000000000
0 3 1 0 1.0
  0.15370703000       1.000000000000

J. Laun, T. Bredow
"BSSE-corrected consistent Gaussian basis sets of triple-zeta valence with polarization 
quality of the sixth period for solid-state calculations", 
J. Comput. Chem. (2021) https://doi.org/10.1002/jcc.26521

Po_pob_TZVP_rev2_SOC

284 12
STUTSC
0 0 5 2 1.0
  6744.82117650       0.000076891556
  744.418925320       0.000712848274
  131.040293090       0.002205758396
  19.6620210300      -0.643647137440
  16.6230256090       0.919971505460
0 0 2 2 1.0
  23.0940029650      -0.070404410177
  6.97073983810       0.978865400860
0 0 2 0 1.0
  1.84973776000       0.675853246983
  0.93082999000       0.324146753017
0 0 1 0 1.0
  0.26927938000       1.000000000000
0 2 3 6 1.0
  253.990244970       0.000083876362
  9.87127187480       0.245727104580
  7.44898934960      -0.442977636610
0 2 4 4 1.0
  8.90273954070      -0.137982504450
  5.74146674650       0.263040053260
  1.98963298230       0.662258461610
  0.94703210822       0.395470518920
0 2 1 0 1.0
  0.35554706000       1.000000000000
0 2 1 0 1.0
  0.15021472000       1.000000000000
0 3 6 10 1.0
  67.9430770460       0.000489191253
  14.9142198940       0.010157120776
  7.29739483050      -0.069943263066
  2.68267844000       0.262447306800
  1.43741430090       0.427023614940
  0.73903797417       0.325024354770
0 3 1 0 1.0
  0.66169712000       1.000000000000
0 3 1 0 1.0
  0.34810921000       1.000000000000
0 3 1 0 1.0
  0.15370703000       1.000000000000

J. Laun, T. Bredow J. Comput. Chem.  (2022), 43:839-846
"BSSE-corrected consistent Gaussian basis sets of triple-zeta valence with polarization quality of the fifth period for solid-state calculation", DOI: 10.1002/jcc.26839
Desmarais, J. K., Flament, J. P., Erba, A. (2020). Spin-orbit coupling in periodic systems with broken time-reversal symmetry: Formal and computational aspects. Physical Review B, 101(23), 235142.

Note: To be used with CRYSTAL23

Po_3s3p2d_SOC

284 8
STUTLC
0 0 3 2. 1
2.549831 -0.093655
1.856210 0.874894
1.374970 -1.246453
0 0 1 0. 1
0.310166 1.0
0 0 1 0. 1
0.149667 1.0
0 2 3 4. 1
2.490870 -0.045917
1.843336 0.285716
1.365434 -0.407404
0 2 1 0. 1
0.296807 1.0
0 2 1 0. 1
0.128541 1.0
0 3 1 0. 1.
 0.9 1.0
0 3 1 0. 1.
 0.3 1.

cite

Desmarais, J. K., Boccuni, A., Flament, J. P., Kirtman, B., & Erba, A. (2023). Perturbation Theory Treatment of Spin–Orbit Coupling. III: Coupled Perturbed Method for Solids. Journal of Chemical Theory and Computation, 19(6), 1853-1863

Desmarais, J. K., Flament, J. P., Erba, A. (2020). Spin-orbit coupling in periodic systems with broken time-reversal symmetry: Formal and computational aspects. Physical Review B, 101(23), 235142.

Note: To be used with CRYSTAL23