Neptunium Basis-Sets:


Np_ERD_SMALL_CORE_PP_4F_IN_VALENCE_NO_G_2017

293 9
INPUT
33. 0 1 1 1 1 1
 16.77194770 541.53853851 0
 9.783552770 191.08457137 0
 9.034226600 146.40258923 0
 7.121848270 60.394333140 0
 13.41832253 -62.62618508 0
0 1 5 8.0 1.0
 131.0309226470 0.01063004059370 0.00768094113575
 38.13007642730 -0.1993706990520 0.00213341195862
 19.98234257180 1.24159919744000 0.06567600384760
 9.718504737580 -2.7678658864100 -0.2595068458490
 5.677738092010 0.50275339742600 -0.2184380006870
0 1 3 8.0 1.0
 7.651397746550 -0.2360465456300 0.05131777836930
 3.588287493100 0.69988751900100 0.52335026513500
 1.731368590790 0.57147616587500 0.38576656731000
0 1 2 0.0 1.0
 1.740114658550 0.07658659264490 0.24517362012000
 0.608021948863 1.12611901078000 0.88205812089500
0 1 1 0.0 1.0
 0.236815296960 1.00000000000000 1.00000000000000
0 3 6 10.0 1.0
 25.53157797220 0.01401361460190
 9.650024940900 -0.0896254877200
 4.373791834070 0.26348966427300
 2.535901578420 0.47664822746700
 1.357074254710 0.29199079570200
 0.922349404616 0.06860626233020
0 3 1 0.0 1.0
 0.317630470474 1.00000000000000
0 4 4 4.0 1.0
 68.21773629300 0.00134829649294
 24.76238342280 0.01120428261590
 10.68265682970 0.02218792618970
 4.807413626220 0.26690889747200
0 4 3 0.0 1.0
 2.370636584020 0.32293879513400
 1.092541429000 0.35319078136600
 0.498202271609 0.22740970833600
0 4 1 0.0 1.0
 0.212366626926 1.00000000000000



Optimized basis set for Np3+ without g (+ more diffuse exponents optimized on NpO cubic peridodic structure)

used in:
1)  Kh. E. El-Kelany, C. Ravoux, J. K. Desmarais, Y. Pan, J. S. Tse, R. Dovesi, and A. Erba, "Magnetic Ordering and Electronic Properties of Strongly Correlated Ln2O3 Sesquioxides (Ln=La, Ce, Pr, Nd)" in preparation

2) J. K. Desmarais, A. Erba, and R. Dovesi, Theor. Chem. Acc. (2018) "Generalization of the Periodic LCAO Approach in the CRYSTAL Code to g-type Orbitals" submitted


Np_ERD_SMALL_CORE_PP_4F_IN_VALENCE_2017

293 11
INPUT
33. 0 1 1 1 1 1
 16.77194770 541.53853851 0
 9.783552770 191.08457137 0
 9.034226600 146.40258923 0
 7.121848270 60.394333140 0
 13.41832253 -62.62618508 0
0 1 5 8.0 1.0
 131.0309226470 0.01063004059370 0.00768094113575
 38.13007642730 -0.1993706990520 0.00213341195862
 19.98234257180 1.24159919744000 0.06567600384760
 9.718504737580 -2.7678658864100 -0.2595068458490
 5.677738092010 0.50275339742600 -0.2184380006870
0 1 3 8.0 1.0
 7.651397746550 -0.2360465456300 0.05131777836930
 3.588287493100 0.69988751900100 0.52335026513500
 1.731368590790 0.57147616587500 0.38576656731000
0 1 2 0.0 1.0
 1.740114658550 0.07658659264490 0.24517362012000
 0.608021948863 1.12611901078000 0.88205812089500
0 1 1 0.0 1.0
 0.236815296960 1.00000000000000 1.00000000000000
0 3 6 10.0 1.0
 25.53157797220 0.01401361460190
 9.650024940900 -0.0896254877200
 4.373791834070 0.26348966427300
 2.535901578420 0.47664822746700
 1.357074254710 0.29199079570200
 0.922349404616 0.06860626233020
0 3 1 0.0 1.0
 0.317630470474 1.00000000000000
0 4 4 4.0 1.0
 68.21773629300 0.00134829649294
 24.76238342280 0.01120428261590
 10.68265682970 0.02218792618970
 4.807413626220 0.26690889747200
0 4 3 0.0 1.0
 2.370636584020 0.32293879513400
 1.092541429000 0.35319078136600
 0.498202271609 0.22740970833600
0 4 1 0.0 1.0
 0.212366626926 1.00000000000000
0 5 1 0.0 1.0
 0.900000000000 1.00000000000000
0 5 1 0.0 1.0
 0.300000000000 1.00000000000000


Optimized basis set for Np3+ with g (+ more diffuse exponents optimized on NpO cubic peridodic structure)

used in:
1)  Kh. E. El-Kelany, C. Ravoux, J. K. Desmarais, Y. Pan, J. S. Tse, R. Dovesi, and A. Erba, "Magnetic Ordering and Electronic Properties of Strongly Correlated Ln2O3 Sesquioxides (Ln=La, Ce, Pr, Nd)" in preparation

2) J. K. Desmarais, A. Erba, and R. Dovesi, Theor. Chem. Acc. (2018) "Generalization of the Periodic LCAO Approach in the CRYSTAL Code to g-type Orbitals" submitted